I'm no expert by any stretch, but here's a few thoughts...
JLawrence: 1) The motors do not seem to power up evenly, and the quad ends up flipping over backward when I try to hover. 2) While holding the throttle constant (say at 20%) two out of the four motors will slowly start to speed up to full throttle.
My throttle problems were due to uncalibrated escs. Search for info on that.
If you have a good combination of motors/prop/batt/weight, you should be able to hold hover at about 50% throttle. See ecalc.ch for help with your config.
Check to be sure when starting on the ground that Baro is NOT turned on. That was my mistake early on. The Baro is trying to maintain altitude (at present ground level) so it was fighting my quad lifting off. Also be sure to starting from as level a surface as possible.
The modes to fly in are viewable and configured using the MultiWiiConf app.
I have horizon on all the time on my board and I then add Baro to Horizon once I am in the air. I use a small black foam pop screen from a headset microphone I wasn't using and positioned it, covering the baro chip (the one with the pinhole in the center). That chip dislikes both light and gusts of wind (prop wash). A microphone pop filter's foam can do just the trick. Search for ways to secure it to your board. Since I have a copper clad pc board over my flight board on standoffs, I wedge the pop screen under the board and secure it using a small loose cable tie. The pc board serves as a base for my gps chip.
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I'm on my mac operating system, so I don't have access to my PID settings at the moment, but I can dig them up if needed. I'm still getting the bugs out of my quad. With an AUW of 1.5kg, I can hover in the wind for 12-13 mins using a 5000mah 30C 3S. My hover seems okay (waiting for a windless day here in SoCal) but the GPS toilet bowls in a 15 foot diameter circle. It also jitters considerably. The baro oscillates up and down about 4 feet when on. With the wind, that could be atmos conditions.
mattjb: I'm having trouble getting my Quad "dialled" in, but think this may be due to some really crappy bearings in my motors.
I had some issues with poor motor mounting, using cable ties to secure them to the wood booms. Once I tightened things down, I got rid of some wobbling on one motor.
Keep at it guys, it definitely gets better. At the least you're learning.